Freeing Up Nitrogen Atoms

Freeing Up Nitrogen Atoms

Nitrogen is an essential ingredient in biological molecules, such as proteins and DNA, but nitrogen must be in a free state for these molecules to form. By that, we mean nitrogen atoms that are not already bonded to each other, making them inert. Seventy-eight percent of our atmosphere consists of nitrogen, but nitrogen atoms in the air are bonded with other nitrogen atoms to form nitrogen molecules that are chemically inert. It takes enormous amounts of energy to tear apart nitrogen molecules, freeing up nitrogen atoms to bond with other elements.

A nitrogen atom can be useful for life when it bonds with three oxygen atoms to make nitrate. Nitrogen can also bond with three hydrogen atoms making ammonia, which is also useful for life. This is a complicated issue because Earth’s early atmosphere did not contain much oxygen, so the rock record shows nitrogen bonded to hydrogen atoms. Ammonia has a very low gram molecular weight, so it can escape Earth’s gravity. We see large amounts of ammonia in the atmospheres of our Jovian planets, but that is because their large masses provide enough gravity to hold on to the ammonia.

Humans create nitrogen fertilizer through chemical and electrical processes. But that method of freeing up nitrogen atoms is complex and requires a lot of energy. Scientists in the past have theorized that microbes could have been the method of nitrogen fixation, reducing the nitrogen to nitrates. This is a “chicken-egg” problem because nitrates had to be in existence for the microbes to exist. Freeing up nitrogen atoms would require some non-biologic processes. Studies have shown that electric discharges in lightning have enough energy to tear apart nitrogen molecules, but the rate is insufficient to account for all the nitrogen needed.

New research on volcanoes has shown that eruptions release oxygen and supply enough energy to tear apart nitrogen molecules that bond with oxygen. The nitrates produced would accumulate, allowing life to survive. Studies have shown that a strong volcanic eruption can produce about 60 million tons of nitrate. In 2022 the Tonga-Hunga Ha’apai volcano in Indonesia produced 400,000 discharges in one day.

As we learn more about the chemistry and physics required for freeing up nitrogen to allow life to exist on this planet, the complexity and design of the system astound many researchers. The Bible merely says God did it, but not how or what complexities were involved. Everywhere we look, we see that a wounder-working hand has gone before. Nitrogen is an excellent example of how much wisdom, power, and planning was required for a life-bearing planet to come into existence.

— John N. Clayton © 2023

Reference: Science News for June 3, 2023, page 7.

Lightning Dynamics and St. Elmo’s Fire

Lightning Dynamics

As an old physics teacher, I am interested in lightning dynamics. Most of us have seen the effects of lightning and have been impressed with its power and destructive potential.

The question is, what produces lightning and its incredible power? On Earth, lightning is caused by water. If you have a steady stream of water from a faucet and bring a charged glass or plastic rod near it, the water stream will move toward the rod. The water molecule is polarized, meaning it has a positive and negative end. The charged rod attracts the oppositely charged end of the water molecule.

When warm moist air rises to form a thunderhead, it can reach velocities of 100 mph. The air cools and forms ice crystals that can become positively charged by collisions with other ice crystals. That means the lower parts of the storm cloud will acquire a negative charge. Conversely, the very bottom of the cloud will generate a positive charge as a result of the negative sections of the cloud. When this charge imbalance becomes great enough, an inch-wide stream of electrons travels between the negative and positive areas. This can be between the two layers of the cloud, the negative midsection and positive bottom of the cloud, or the ground and the positive lower parts of the cloud. This stream of electrons typically moves at 200,000 mph.

Lightning dynamics can heat the air around the stream of electrons to 50,000 degrees Fahrenheit, turning oxygen into ozone and sending out a shock wave which we hear as thunder. A tall object like a tree, a church steeple, or a lightning rod will accumulate a charge because it is closest to the charged cloud. Sometimes charges around the tall object will cause the air to glow in what is called “St. Elmo’s Fire.” That name is credited to a monk who first recorded seeing it at the top of his church and thought he was having a vision.

Lightning dynamics are very complicated and not a threat to humans unless we are careless. However, lightning has various benefits, such as producing nitrogen fixation so that plants can grow and resupplying the ozone layer, protecting us from some of the dangers coming to Earth from outer space.

— John N. Clayton © 2022

Reference: “Seconds count when lightning is spotted” in The Herald Bulletin, Anderson, Indiana, August 13, 2022, page C3.

Lightning Is a Useful Tool in God’s Creation

Lightning Is a Useful Tool in God’s Creation
Gigantic jet as seen from the summit of Mauna Kea, Hawaii

We previously discussed the discovery that hydroxyl radicals are natural agents that clean the atmosphere. They help remove some of the pollution that humans cause. The hydroxyl radicals are produced by lightning. People often see lightning as a harmful and destructive agent on planet Earth. However, lightning is a useful tool in God’s creation.

NASA’s “Astronomy Picture of the Day” for September 29, 2021, featured an interesting article about a type of lightning called gigantic jets. The gigantic jet shown on the APOD post moved roughly 70 kilometers in just under a second. These gigantic jets are different from the common lightning traveling from cloud to cloud or cloud to ground that we all have seen. We are less familiar with other types of lightning known as blue jets, red sprites, and these gigantic jets.

As we have said before, lightning is also part of the nitrogen-fixing system in Earth’s atmosphere. Lightning converts the nitrogen that makes up 78% of our air into the nitrates essential for plant growth. Thus, lightning is a useful tool in God’s creation to help produce our food and clean our air.

— John N. Clayton © 2021

Use THIS LINK to see the APOD posting with a video of a gigantic jet.

Good Soils Are Vital for Survival

Good Soils Are Vital for Survival

Many years ago in Alaska, I had a discussion with a biologist who was studying the Alaskan soils. His study revolved around the fact that Alaska has very little soil and what it does have is developing. The lack of soil in Alaska has limited plant growth and made the ecology dependent on migrating salmon. Soils are complex mixtures of organic matter, minerals, water, air, and billions of organisms that form over hundreds of years. Good soils are vital for survival. President Franklin D. Roosevelt once said, “A nation that destroys its soils destroys itself.”

Research has shown that plants are designed to “call” for nutrients from the soil. A plant will release molecules called flavonoids, which cause bacteria in the soil to migrate into the plant and form nitrogen nodules on the roots. The nitrogen nodules generate food for the plant. If ample nitrogen is already available for the plant, it will not release the flavonoids.

This “hunger” by plants is vital to understand because many natural and human-caused processes can deplete the soil. Forest and brush fires, hurricanes, pollution, and climate change can deplete soils’ nitrogen content and kill plants. Studies of the giant sequoias in California have shown that the soil under them has twice as many bacteria as the soil under nearby sugar pines. We all know that bacteria influence human health, but bacteria also affect plant health and growth.

As our population increases and world climates change, it will become increasingly important to understand how soil allows us to feed our growing population. God’s design of the Earth includes providing the soils necessary to produce food. Good soils are vital for survival.

— John N. Clayton © 2020

Reference: The National Science Foundation post on October 14, 2020.

Nitrogen Fixation and Life

Nitrogen Fixation and Life

There are many chemical wonders in our world, but few are as important and complex as the chemistry of nitrogen. Nitrogen makes up 78% of our atmosphere. It combines with oxygen to form nitrates and with hydrogen to produce ammonia, both of which are essential for growing our food. Nitrogen fixation, which is how nitrogen gets from what we breathe to what we eat, is an amazing demonstration of design.

First, let us review a little high school chemistry. The atoms of all elements have electrons which give them their properties for forming compounds. The electrons are arranged in pairs with their magnetic poles designed so that in a stable arrangement, one electron’s north pole is matched with its neighboring electron’s south pole. The electrons have various orbitals with different energy levels. The atom is stable and chemically inert if an orbital is filled with all the paired electrons it can hold. For example, neon has 10 electrons. The first two orbitals each have two paired electrons, and the last orbital has six electrons in three pairs. This pairing of electrons makes neon an inert gas which does not combine chemically with other elements.

Nitrogen has an uneven number of seven electrons. So how does nitrogen become chemically stable? The answer is that two nitrogen atoms share three electrons, giving them stability. The two nitrogen atoms bond together to form a diatomic molecule that cannot be easily pulled apart to bond with other elements. How strong is the bonding? To break up a nitrogen molecule into two nitrogen atoms requires temperatures of 400 to 500 degrees Celsius and pressures of 200 atmospheres. So with nitrogen as the dominant element in our atmosphere, the atmospheric gases are stable and inert. Also, nitrogen is not a greenhouse gas that could threaten our temperatures on Earth. How then has God built a system that takes these stable nitrogen molecules and breaks their triple bonds to produce nitrates and ammonia?

If you think this isn’t an important subject, ask yourself where your food comes from? The answer is that 50% of the American diet is produced using artificial fertilizers containing nitrogen, which has been “fixed.” Nitrogen fixation combines that inert gas with oxygen and/or hydrogen to supply the soil with the chemical needed to grow the plants we eat, and which the livestock eat to provide us with meat.

Bacteria accomplish God’s method of nitrogen fixation. The bacteria turn nitrogen into ammonia, which is a nitrogen atom sharing electrons with three hydrogen atoms instead of with another nitrogen atom. Plants known as legumes such as soybeans and peas, as well as bayberry and alder trees, attract bacteria which concentrate in nodules on the plant’s roots. The bacteria turn nitrogen gas into ammonia and nitrates the plants can use. Cyanobacteria in the ocean and cycad plants on the land are also major nitrogen fixers. Scientists are also discovering tropical plants that contribute to the wealth of nitrogen compounds in the soil.

Most of our fertilizers have nitrogen fixed by a method called the Haber-Bosch process. It uses massive amounts of energy to break the triple bonds of nitrogen gas. Producing 500 degrees and 200 atmospheres is expensive, and that is why you pay so much for the fertilizer you use in your garden. God’s methods are free. Scientists are trying to figure out how to recreate God’s nitrogen fixation method to save energy and produce more food.

Many bacteria are beneficial in various ways, and nitrogen fixation is only one of them. This is a great apologetic for God’s wisdom and design in preparing the Earth to provide food for us to eat.

— John N. Clayton © 2020

An excellent article on this topic titled “Out of Thin Air” was published in Science News, April 12, 2008. It is available online at THIS LINK, but a subscription is required to read it.

Nitrogen Mystery Answered

Nitrogen Mystery Answered
One of the great mysteries of the past 1000 years of soil studies has apparently been answered. The great nitrogen mystery is how nitrogen gets into the soil. Plants need nitrogen, and they need it in the form of nitrates and other compounds essential to plant growth.

Most of us put fertilizer on our plants to make them healthy and don’t think about the fact that while our atmosphere is 78% nitrogen, plants can’t absorb the nitrogen directly from the air. In high school, we learned about “nitrogen fixation” and were told about nitrogen-fixing bacteria and the role of lightning in transforming atmospheric nitrogen into forms that could be used by plants.

Plant scientists have known that this model was not complete. The nitrogen cycle clearly had some missing parts, and our knowledge of how nitrogen gets into the soil was obviously lacking. Scientists have now discovered that a significant portion of getting nitrogen to plants involves seeping through bedrock. Nitrogen becomes trapped in sedimentary rocks in the oceans. When tectonic activity lifts the sedimentary rocks, so they are at the surface of the Earth, they begin to release their nitrogen to the soils above them, Studies in California show that soils above sedimentary rocks contain 50% more nitrogen than soils above volcanic rocks.

This discovery is a breakthrough in soil chemistry and has strong implications for how we can accelerate plant growth. Choosing places suitable for agriculture can be made more accurate with this new understanding. The complexity of Earth’s various cycles to allow for plant growth and to provide for human needs is astounding. Even such a fundamental question as the nitrogen mystery is still revealing God’s wisdom and planning in providing a life-supporting planet for us to live.
–John N. Clayton © 2018
Reference: Scientific American, July 2018, page 15-17.

We Need Lightning to Survive on Earth

We Need Lightning
Most of us have had some experience with lightning. The chances are that our experiences have been terrifying and destructive, and we may view lightning as a bad thing. You may wonder if we need lightning. The short answer is, “Yes.” Lightning is a good thing, and there are many things we are still learning about it.

Lightning helps produce the nitrates and other nitrogen compounds that are needed by all living things on Earth. The process is called “nitrogen fixation, ” and it is vital to our very existence. Water droplets in the air carry an electric charge. That charge can accumulate to dangerous levels unless there is a way to neutralize it. That’s where lightning comes in.

One of my favorite demonstrations as a physics teacher was to get a very small flow of water going from a faucet and then bring a charged rod up to the column of water. The stream of water will bend in response to the charge. That is because the polar nature of the water molecule allows it to have electrical properties. Because of water’s electrical property, lightning is generated to release nitrogen from the air and deposit it in the crust of the Earth as nitrates and other nitrogen compounds that plants need to grow. The plants then feed and protect the animals and us.

Low Earth orbit satellites and high flying airplanes have recently made us aware of other properties of lightning. We have learned that red sprites occur and they have been photographed above large thunderstorms. Other upper atmosphere lightning phenomena include blue jets and terrestrial gamma flashes. Scientists are studying the highly complex nature of lightning to understand how the system works.

The Bible makes many comments about lightning. It tells us that lightning is made with water (rain) even though people at that time totally ascribed lightning to supernatural causes. (See Jeremiah 10:13 and 51:16). Lightning is referred to as a tool of God. (See Job 28:26; 36:30; 37:3, 11, 15; 38:24, 25, 35.)

We are just beginning to understand the design of Earth’s atmosphere and why we need lightning. It continues to be obvious that the more we know of the creation, the closer we get to understanding the power and wisdom of the Creator.
–John N. Clayton © 2017